Title |
Accuracy Improvement for Measurement of Heat of Fusion by T-history Method |
Keywords |
Phase change material ; 상변화물질 ; Heat of fusion ; 융해열 ; Latent heat ; 잠열 ; T-history method ; T-history법 ; Thermal storage ; 열저장 |
Abstract |
T-history method, measuring heat-of-fusion of phase change material(PCM) in sealed tubes, has the advantages of a simple experimental device and no requirements in sampling process. However, a degree of supercooling used in selecting the range of latent heat release and neglecting sensible heat during the phase change process can cause significant errors in determining the heat of fusion in the original method, which has been improved in order to predict better results by us. In the present study, the modified method was applied to a variety of PCM such as paraffin and lauric acid having very small or no supercooling with a satisfactory precision. Also the selection of inflection point and temperature measurement position was turned out not to affect the accuracy of heat-of-fusion significantly. As a result, the method can provide an appropriate means to assess a new developed PCM by cycle test even if a very accurate value cannot be obtained. |